Can a GPC card be used to pay for the dry cleaning of these items?
These are the types of actions the GPC was designed to handle.
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13.301 -- Governmentwide Commercial Purchase Card.
(a) Except as provided in 32.1108(b)(2), the Governmentwide commercial purchase card is authorized for use in making and/or paying for purchases of supplies, services, or construction. The Governmentwide commercial purchase card may be used by contracting officers and other individuals designated in accordance with 1.603-3. The card may be used only for purchases that are otherwise authorized by law or regulation.
Since these table cloths are government property and used for official government functions, use of the card by an authorized card holder is appropriate.