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Where do I find info on Explosive HAZARD / Chemical Sign requirement for outdoor open storage; size, visual placement location, size, durability, same symbol upon approach and leaving (instead of 2 different HAZARD signs) and should they be reflective? I wasn't sure if 49 CFR 172.519 applies?
DA PAM 385-64 6-13 "Firefighting guidance symbols" should provide the guidance you are looking for. I did not see the requirement for refectivity.
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